SCATTERING OF ROTATIONALLY ALIGNED OXYGEN MOLECULES AND THE MEASUREMENT OF ANISOTROPIES OF VAN-DER-WAALS FORCES

被引:53
作者
AQUILANTI, V
ASCENZI, D
CAPPELLETTI, D
FRANCESCHINI, S
PIRANI, F
机构
[1] Dipartimento di Chimica dell'Università, 06123 Perugia
关键词
D O I
10.1103/PhysRevLett.74.2929
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Measurements are reported for the scattering of molecular oxygen with both a hot rotational energy distribution and cooled at its ground rotational state with a controlled alignment of the rotational angular momentum. The cooling and control of the alignment are achieved using supersonic expansion in beams of molecular oxygen seeded in various mixtures of Ne, He, and H2 and monitored by a Stern-Gerlach magnetic deflection technique. It is shown by the example of integral scattering cross section with Xe in the glory energy range that information can be obtained on the isotropic and anisotropic components of intermolecular van der Waals interactions. © 1995 The American Physical Society.
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页码:2929 / 2932
页数:4
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共 17 条
  • [1] Sinha M.P., Caldwell C.D., Zare R.N., J. Chem. Phys., 61, (1975)
  • [2] Visser A.G., Bekooy J.P., van der Meij L.K., de Vreugd C., Korving J., Chem. Phys., 20, (1977)
  • [3] Sanders W.R., Anderson J.B., J. Phys. Chem., 88, (1984)
  • [4] Rubahn H.G., Toennies J.P., J. Chem. Phys., 89, (1988)
  • [5] Pullman D.P., Herschbach D.R., 90, (1989)
  • [6] Pullman D.P., Friedrich B., Herschbach D.R., 93, (1990)
  • [7] Friedrich B., Pullman D.P., Herschbach D.R., J. Phys. Chem., 95, (1991)
  • [8] Saleh H.J., McCaffery A.J., J. Chem. Soc. Faraday Trans., 89, (1993)
  • [9] Weida M.J., Nesbitt D.J., Collisional alignment of CO2 rotational angular momentum states in a supersonic expansion, The Journal of Chemical Physics, 100, (1994)
  • [10] Aquilanti V., Ascenzi D., Cappelletti D., Pirani F., Nature (London), 371, (1994)