SYNTHESIS OF PYRIDINE PYRIDINIUM-BASED ALKYNYL MONOMERS, OLIGOMERS AND POLYMERS - ENHANCING CONJUGATION BY PYRIDINE N-QUATERNIZATION

被引：19

作者：

BUNTEN, KA ^{[1
]}

KAKKAR, AK ^{[1
]}

机构：

[1] MCGILL UNIV,DEPT CHEM,MONTREAL,PQ H3A 2K6,CANADA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 11期

关键词：

D O I：

10.1039/jm9950502041

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Quaternization of the pyridine nitrogen in 2,5- and 2,6-diethynylpyridine-based organic and organometallic monomers, oligomers and polymers via solution nucleophilic substitution reactions yields stable pyridinium analogues, and enhances pi-electron delocalization along the backbone as evidenced by strong red shifts in the UV-VIS absorption spectra.

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页码：2041 / 2043

页数：3

相关论文

共 12 条

[1]

Bredas J. L., 1990, NATO ASI SER C-MATH, P182

[2] OXIDATIVE POLYMERIZATION OF DIETHYNYL COMPOUNDDS [J].

HAY, AS .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1969, 7 (7PA1) :1625-&

[3] SYNTHESIS AND OPTICAL SPECTROSCOPY OF LINEAR LONG-CHAIN DI-TERMINAL ALKYNES AND THEIR PT-SIGMA-ACETYLIDE POLYMERIC COMPLEXES [J].

KHAN, MS ;

KAKKAR, AK ;

LONG, NJ ;

LEWIS, J ;

RAITHBY, P ;

NGUYEN, P ;

MARDER, TB ;

WITTMANN, F ;

FRIEND, RH .

JOURNAL OF MATERIALS CHEMISTRY, 1994, 4 (08) :1227-1232

[4] ORGANOMETALLIC COMPOUNDS FOR NONLINEAR OPTICS - THE SEARCH FOR EN-LIGHT-ENMENT [J].

LONG, NJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (01) :21-38

[5] SYNTHESIS OF REGIOREGULAR POLY(METHYL PYRIDINIUM VINYLENE) - AN ISOELECTRONIC ANALOG TO POLY(PHENYLENE VINYLENE) [J].

MARSELLA, MJ ;

FU, DK ;

SWAGER, TM .

ADVANCED MATERIALS, 1995, 7 (02) :145-147

[6] RIGID-ROD CONJUGATED POLYMERS FOR NONLINEAR OPTICS .1. CHARACTERIZATION AND LINEAR OPTICAL-PROPERTIES OF POLY(ARYLENEETHYNYLENE) DERIVATIVES [J].

MORONI, M ;

LEMOIGNE, J ;

LUZZATI, S .

MACROMOLECULES, 1994, 27 (02) :562-571

[7] POLY(2,5-ETHYNYLENETHIOPHENEDIYLETHYNYLENES), RELATED HETEROAROMATIC ANALOGS, AND POLY(THIENO[3,2-B]THIOPHENES) - SYNTHESIS AND THERMAL AND ELECTRICAL-PROPERTIES [J].

RUTHERFORD, DR ;

STILLE, JK ;

ELLIOTT, CM ;

REICHERT, VR .

MACROMOLECULES, 1992, 25 (09) :2294-2306

[8]

Skotheim T. A., 1986, HDB CONDUCTING POLYM

[9] STUDIES ON POLYYNE POLYMERS CONTAINING TRANSITION-METALS IN THE MAIN CHAIN .7. SYNTHESIS AND CHARACTERIZATION OF PALLADIUM-POLYYNE POLYMERS [J].

TAKAHASHI, S ;

MORIMOTO, H ;

MURATA, E ;

KATAOKA, S ;

SONOGASHIRA, K ;

HAGIHARA, N .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1982, 20 (02) :565-573

[10] A CONVENIENT SYNTHESIS OF ETHYNYLARENES AND DIETHYNYLARENES [J].

TAKAHASHI, S ;

KUROYAMA, Y ;

SONOGASHIRA, K ;

HAGIHARA, N .

SYNTHESIS-STUTTGART, 1980, (08) :627-630