COMPLEXES [(P-2)RH(HFACAC)] (P-2=BIDENTATE CHELATING PHOSPHANE, HFACAC=HEXAFLUOROACETYLACETONATE) AS CATALYSTS FOR CO2 HYDROGENATION - CORRELATIONS BETWEEN SOLID-STATE STRUCTURES, RH-103 NMR SHIFTS AND CATALYTIC ACTIVITIES

被引：96

作者：

FORNIKA, R

GORLS, H

SEEMANN, B

LEITNER, W

机构：

[1] UNIV JENA,MAX PLANCK GESELL FORDERUNG WISSENSCH,ARBEITSGRP CO2 CHEM,D-07743 JENA,GERMANY

[2] BRUKER ANALYT MEATECH GMBH,D-76287 RHEINSTETTEN,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 14期

关键词：

D O I：

10.1039/c39950001479

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexes [(P-2)Rh(hfacac)] 1a-h are the most effective catalyst precursors for catalytic hydrogenation of CO2 to formic acid in organic solvents allowing turnover frequencies of up to 1335 h(-1); Rh-103 NMR shifts of these complexes in solution are mainly determined by the P-Rh-P angle as obtained from solid state structures and have predictive potential for the catalytic activity of structurally related phosphanes PP

引用

页码：1479 / 1481

页数：3

共 30 条

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