INTERFEROMETRIC MEASUREMENTS OF THE DIPOLE POLARIZABILITY-ALPHA OF MOLECULES BETWEEN 300-K AND 1100-K .2. A NEW METHOD FOR MEASURING THE DISPERSION OF THE POLARIZABILITY AND ITS APPLICATION TO AR, H-2, AND O-2

被引:52
作者
HOHM, U [1 ]
KERL, K [1 ]
机构
[1] TECH UNIV BRAUNSCHWEIG,INST PHYS & THEORET CHEM,HANS SOMMER STR 10,W-3300 BRAUNSCHWEIG,GERMANY
关键词
D O I
10.1080/00268979000100621
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new interferometric method is used to determine the temperature dependence of the dispersion of the polarizability a of gaseous argon, hydrogen and oxygen, respectively. Although only the small wavelength range between 543-51 nm and 632-99 nm is covered, the data obtained in the temperature range 300K < T < 1010K are useful to derive important molecular properties like effective oscillator strengths and excitation energies, dispersion energy constants, and polarizability derivatives. © 1990 Taylor & Francis Ltd.
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页码:819 / 831
页数:13
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