REVERSIBLE OPENING OF A TRINUCLEAR HETEROMETAL CLUSTER

被引：115

作者：

HUTTNER, G

SCHNEIDER, J

MULLER, HD

MOHR, G

SEYERL, JV

WOHLFAHRT, L

机构：

[1] Fachbereich Chemie der Universität Konstanz, Konstanz, D-7750

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 01期

关键词：

D O I：

10.1002/anie.197900761

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mode of action of metal clusters in homogeneous catalysis is hardly known. The first proof that clusters can reversibly add substrates (LCO, PPh3) via opening of metal‐metal bonds has now been obtained. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：76 / 77

页数：2

共 13 条

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[7] HUTTNER G, 1976, ANGEW CHEM, V88, P719
[8] ACTIVATION OF HYDROCARBONS BY UNSATURATED METAL CLUSTER COMPLEXES .3. INTERACTION OF H2OS3(CO)10 WITH ALKENES - INTERMEDIATES IN HYDROGENATION AND CARBON-HYDROGEN BOND ACTIVATION
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (04) : 1056 - 1057
[9] Muetterties E. L., 1978, ANGEW CHEM, V90, P577
[10] COORDINATION CHEMISTS VIEW OF SURFACE SCIENCE
MUETTERTIES, EL
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (08): : 545 - 558

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