RADICAL CATIONS - GENERATION BY PHOTOCHEMICAL ELECTRON-TRANSFER AND FRAGMENTATION

被引：28

作者：

ALBINI, A ^{[1
]}

FASANI, E ^{[1
]}

DALESSANDRO, N ^{[1
]}

机构：

[1] UNIV PAVIA, DEPT ORGAN CHEM, I-27100 PAVIA, ITALY

来源：

COORDINATION CHEMISTRY REVIEWS | 1993年 / 125卷 / 1-2期

关键词：

D O I：

10.1016/0010-8545(93)85024-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The high oxidizing power of excited states allows the preparation of radical cations in solution under mild conditions. These species often fragment competitively with back electron transfer and yield a radical and a cation. The selectivity of the process and the novel chemical reactions obtained is this ways are discussed through examples mainly using aryl nitriles as acceptors and benzyl derivatives as donors.

引用

页码：269 / 281

页数：13

共 98 条

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