SYNTHESIS AND RESOLUTION OF HETEROCHELATE METAL COMPLEXES OF CHROMIUM(3) AND COBALT(3) WITH LIGANDS 2,2/-BIPYRIDINE,1,10-PHENANTHROLINE, AND OXALATE ION

被引：51

作者：

BROOMHEAD, JA

DWYER, M

KANEMAGU.N

机构：

[1] Chemistry Department, School of General Studies, Australian National University, Canberra, A.C.T.

[2] Chemistry Department, University of Queensland, St. Lucia, Brisbane, Queensland

来源：

INORGANIC CHEMISTRY | 1968年 / 7卷 / 07期

关键词：

D O I：

10.1021/ic50065a025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New heterochelate complex cations Cr(ox)(bipy)2+, Cr(ox)(phen)2+, Co(ox)(bipy)2+, and Co(ox)(phen)2+ (ox = oxalate ion, bipy = 2,2′-bipyridine, phen = 1,10-phenanthroline) have been prepared as their chloride, perchlorate, or iodide salts and resolved by means of optically active Cr(ox)2phen-. The anionic complexes Co(ox)2bipy- and Co(ox)2phen- have also been obtained in combination with either Ba2+ or Co(ox)(phen)2+, respectively. All of the optically active cations have been found to racemize in solution and in addition the cobalt(III) complexes were markedly photosensitive. © 1968, American Chemical Society. All rights reserved.

引用

页码：1388 / +

页数：1

共 10 条

[1] ABLOV AV, 1962, RUSS J INORG CHEM, V7, P1304
[2] Bailar J. C., 1939, INORG SYNTH, V1, P35
[3] SYNTHESIS AND CHARACTERISATION OF DIACIDOBIS(ETHYLENEDIAMINE)RUTHENIUM(3) COMPLEXES AND RELATED COMPOUNDS
BROOMHEAD, JA
KANEMAGU.LA
[J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (04): : 546 - +
[4] PREPARATION AND RESOLUTION OF BIS(OXALATO)-2,2'-BIPHYRIDINECHROMATE(III) AND BIS(OXALATO)-1,10-PHENANTHROLINECHROMATE(III) IONS
BROOMHEAD, JA
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1962, 15 (02) : 228 - &
[5] RACEMIZATION STUDIES ON BIS(OXALATO)2,2'-BIPYRIDINE-CHROMATE (3) AND BIS(OXALATO)1,10-PHENANTHROLINE CHROMATE (3) IONS
BROOMHEAD, JA
[J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1965, 27 (09): : 2049 - +
[6] STUDIES IN CO-ORDINATION CHEMISTRY .13. MAGNETIC MOMENTS AND BOND TYPES OF TRANSITION-METAL COMPLEXES
BURSTALL, FH
NYHOLM, RS
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1952, (SEP): : 3570 - 3579
[7] FIGGIS BN, 1966, INTRO LIGAND FIELDS, P163
[8] RESEARCHES ON AMMINES .10. TRIAMMINES OF BIVALENT PLATINUM
KING, HJS
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1948, (NOV): : 1912 - 1916
[9] OPTICALLY ACTIVE TRIS(1,10-PHENANTHROLINE) COMPLEXES OF CHROMIUM(3) AND COBALT(3) BY RESOLUTION AND SYNTHESIS
LEE, CS
GORTON, EM
NEUMANN, HM
HUNT, HR
[J]. INORGANIC CHEMISTRY, 1966, 5 (08) : 1397 - &
[10] INFRARED SPECTRA OF METALLIC COMPLEXES .4. COMPARISON OF THE INFRARED SPECTRA OF UNIDENTATE AND BIDENTATE METALLIC COMPLEXES
NAKAMOTO, K
FUJITA, J
TANAKA, S
KOBAYASHI, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (18) : 4904 - 4908

← 1 →