ORGANOMETALLIC REACTIONS .16. TRIHALOGENOMETHYLTIN COMPOUNDS - THEIR PREPARATIONS, PROPERTIES, AND REACTIONS

被引：20

作者：

DAVIES, AG

MITCHELL, TN

机构：

[1] William Ramsay and Ralph Forster Laboratories, University College

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 14期

关键词：

D O I：

10.1039/j39690001896

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Trialkyl(diethylamino)tin compounds react readily with halogenoforms to give the corresponding trialkyl(trihalogenomethyl)tins, R3Sn· CX3; these can then be reduced by trialkyltin hydrides or by lithium aluminium hydride to give the di- and mono-halogenomethyltin compounds, R 3Sn·CHX2 and R3Sn·CH 2X. respectively. Some properties and reactions of these products have been investigated.

引用

页码：1896 / &

共 24 条

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