SYNTHESIS AND SOLUTION CHARACTERIZATION OF ANTIMONY POLYESTERS

被引：15

作者：

CARRAHER, CE ^{[1
]}

BLAXALL, HS ^{[1
]}

机构：

[1] UNIV S DAKOTA,DEPT CHEM,VERMILLION,SD 57069

来源：

ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1979年 / 83卷 / DEC期

关键词：

D O I：

10.1002/apmc.1979.050830103

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of antimony polyesters occurs under quite specific conditions utilizing the interfacial technique. Reaction is second order with specific rate constants in the (Formula Presented.) range of 10−1 to 101 1/mol·s. Molecular weight is independent of reaction time. Reaction rate increases as the reaction liquid phase volume increases. The products are oligomeric to polymeric with weight average molecular weights of 3 to 100 × 103. Many products exhibit low viscous drag compared with chain length. The products are near semiconductors. © 1979 Hüthig & Wepf Verlag, Basel

引用

页码：37 / 45

页数：9

共 21 条

[1] FACTORS AFFECTING INHIBITION OF PHOSPHOFRUCTOKINASE ACTIVITY OF SCHISTOSOMA MANSONI BY TRIVALENT ORGANIC ANTIMONIALS [J].