SELECTIVE OXIDATION OF STEROIDAL HOMOALLYLIC ALCOHOLS USING PYRIDINIUM CHLOROCHROMATE (PPC)

被引：17

作者：

PARISH, EJ

LUO, C

PARISH, S

HEIDEPRIEM, RW

机构：

[1] Department of Chemistry, Auburn University, AL

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 19期

关键词：

D O I：

10.1080/00397919208021550

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Pyridinium chlorochromate (PCC), in the presence of anhydrous calcium carbonate, has been found to be an effective and convenient reagent for the selective oxidation of steroidal homoallylic alcohols to the corresponding beta, delta-unsaturated ketones in good yield.

引用

页码：2839 / 2847

页数：9

共 26 条

[1] METAL CATALYSIS IN OXIDATION BY PEROXIDES .28. ANIONIC MOLYBDENUM-PICOLINATE N-OXIDO-PEROXO COMPLEX - AN EFFECTIVE OXIDANT OF PRIMARY AND SECONDARY ALCOHOLS IN NONPOLAR-SOLVENTS [J].