EXCESS VOLUMES, SPEEDS OF SOUND, AND VISCOSITIES FOR MIXTURES OF 1,2-ETHANEDIOL AND ALKOXY ALCOHOLS WITH WATER AT 308.15-K

被引:51
作者
REDDY, VK [1 ]
REDDY, KS [1 ]
KRISHNAIAH, A [1 ]
机构
[1] SRI VENKATESWARA UNIV,DEPT CHEM,TIRUPATI 517502,ANDHRA PRADESH,INDIA
关键词
D O I
10.1021/je00015a051
中图分类号
O414.1 [热力学];
学科分类号
摘要
Excess volume, speed of sound, and viscosity data of binary liquid mixtures of water + 1,2-ethanediol, + 2-methoxyethanol, + 2-ethoxyethanol, and + 2-butoxyethanol have been measured at 308.15 K. The results are used to derive densities and isentropic compressibilities. The excess volumes and deviations in the compressibility are negative while deviations in the viscosity are positive for all four systems. The results are discussed in terms of molecular interactions between like and unlike components.
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页码:615 / 617
页数:3
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