THIAZOLE-BASED SYNTHESIS OF C-GLYCOSYL ALDEHYDES

被引：39

作者：

DONDONI, A

SCHERRMANN, MC

机构：

[1] Dipartimento di Chimica, Laboratorio di Chimica Organica, Università, Ferrara

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 45期

关键词：

SUGAR LACTONES; SUGAR ALDEHYDES; C-GLYCOSIDES; THIAZOLE; C-GLYCOSIDATION; FORMYLATION;

D O I：

10.1016/S0040-4039(00)79319-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The formylation at the anomeric carbon of the model sugars 2,3,4,6-tetra-O-benzyl-D-glucopyranose and 2,3:5,6-di-O-isopropylidene-D-mannofuranose is carried out by addition of 2-lithiothiazole to the corresponding lactones followed by reductive dehydroxylation and thiazole to formyl deblocking.

引用

页码：7319 / 7322

页数：4

共 20 条

[1]

ASPINAL GO, 1992, 16TH INT CARB S PAR, pA162

[2] SYNTHESIS OF C-DISACCHARIDES [J].