FLUOROSULFURIC ACID SOLVENT SYSTEM .6. SOLUTIONS OF PHOSPHORUS ARSENIC BISMUTH AND NIOBIUM PENTAFLUORIDES AND TITANIUM TETRAFLUORIDE

被引：31

作者：

GILLESPIE, RJ

OUCHI, K

PEZ, GP

机构：

[1] Department of Chemistry, McMaster University, Hamilton, Ontario

来源：

INORGANIC CHEMISTRY | 1969年 / 8卷 / 01期

关键词：

D O I：

10.1021/ic50071a015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Conductivity measurements on solutions of PF5, AsF5, BiF5, NbF5, PF5-SO3, NbF5-SO3, and AsF5·SO3 are reported. Conductometric titrations have been carried out on solutions of AsF5, BiF5, and AsF5-SO3. The results are compared with those obtained previously for SbFs and SbF5-S03. It is concluded that acid strength increases in the order: PF5 ~NbF5 < TiF4 ~ AsF5 < BiF5 < AsF4(SO3F) < SbF6 < AsF2(SO3F)3 < SbF2(SO3F)3. © 1969, American Chemical Society. All rights reserved.

引用

页码：63 / +

页数：1

共 5 条

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[2] BRAUER G, 1963, HANDBOOK PREPARATIVE, V1, P202
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[4] CHEMISTRY IN SUPER ACIDS .I. HYDROGEN EXCHANGE AND POLYCONDENSATION OF METHANE AND ALKANES IN FSO3H-SBF5 (MAGIC ACID) SOLUTION . PROTONATION OF ALKANES AND INTERMEDIACY OF CH5+ AND RELATED HYDROCARBON IONS . HIGH CHEMICAL REACTIVITY OF PARAFFINS IN IONIC SOLUTION REACTIONS
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (10) : 2726 - +
[5] FLUOROSULFURIC ACID SOLVENT SYSTEM .2. SOLUTIONS OF ANTIMONY PENTAFLUORIDE ANTIMONY TETRAFLUORIDE MONOFLUOROSULFATE AND ANTIMONY PENTAFLUORIDE-SULFUR TRIOXIDE MIXTURES
THOMPSON, RC
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[J]. INORGANIC CHEMISTRY, 1965, 4 (11) : 1641 - &

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