CONDUCTANCE OF KIO3 IN GLYCEROL-WATER MIXTURES

被引：19

作者：

SADEK, H

HAFEZ, AM

KHALIL, FY

机构：

[1] Chemistry Department, Faculty of Science, Alexandria University, Alexandria

来源：

ELECTROCHIMICA ACTA | 1969年 / 14卷 / 11期

关键词：

D O I：

10.1016/0013-4686(69)80036-8

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The conductance of potassium iodate in glycerol-water mixtures at 25°C in the dielectric constant range 55·6 < D < 78·5 has been measured. The Fuoss-Onsager theory is applied to the conductance data and the characteristic functions are derived. The association constant and the a0 parameter increase as the dielectric constant decreases. The plot of log KA against D-1 is not linear, indicating that solvent-separated ion pairs are found in a system characterized by strong hydrogen bonding. © 1969.

引用

页码：1089 / &

共 20 条

[1] ION PAIRS AND SOLVENT-SOLUTE INTERACTION .I. CONDUCTANCE OF LITHIUM CHLORATE IN WATER-DIOXANE MIXTURES AT 25 DEGREES [J].