SYNTHESIS AND CRYSTAL-STRUCTURE OF [(PH3P)2N][NI2(CO)6H]

被引：27

作者：

LONGONI, G ^{[1
]}

MANASSERO, M ^{[1
]}

SANSONI, M ^{[1
]}

机构：

[1] UNIV MILAN,IST CHIM GEN,I-20133 MILAN,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 174卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)91513-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interstitial dihydride dianion [Ni12(CO)21H2]2- is readily converted by carbon monoxide (25°C, 1 atm) into a mixture of tetracarbonylnickel and a new colourless hydride carbonyl monoanion, which has been characterized by X-ray diffraction as [Ni2(CO)6H]-. © 1979.

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页码：C41 / C44

页数：4

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