METAL CATALYSIS IN ALIPHATIC ISOCYANATE-ALCOHOL REACTIONS

被引：14

作者：

OBERTH, AE

BRUENNER, RS

机构：

[1] Research and Technology Department, Aerojet-General Corp., Sacramento

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS | 1969年 / 8卷 / 03期

关键词：

D O I：

10.1021/i160031a003

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A number of metal catalysts for the aliphatic isocyanate-alcohol reaction were studied. Partial alcoholysis of the metal compound is required for the activation of the alcohol. Compounds which suppress alcoholysis also reduce the catalytic activity. The equilibrium involving the alcoholytic products can account for the effects of concentration of catalyst, alcohol, and alcoholytic products on the rate of the catalyzed reaction. © 1969, American Chemical Society. All rights reserved.

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页码：383 / &

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