REACTIONS OF SECONDARY-AMINES WITH TRIOSMIUM DECACARBONYL BIS(ACETONITRILE) - ROOM-TEMPERATURE C-H ACTIVATION AND TRANSALKYLATION

被引：50

作者：

ROSENBERG, E

KABIR, SE

HARDCASTLE, KI

DAY, M

WOLF, E

机构：

[1] Department of Chemistry, California State University, Northridge, Northridge

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 08期

关键词：

D O I：

10.1021/om00158a018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of secondary aliphatic amines with triosmium decacarbonyl bis(acetonitrile) yield a range of trinuclear products that result from transalkylation and/or carbon-hydrogen bond activation of the alkyl groups on the amine. The nature of the products obtained is remarkably sensitive to the structure and steric requirements of the amine employed. © 1990, American Chemical Society. All rights reserved.

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页码：2214 / 2217

页数：4

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