MICROWAVE-SPECTRUM AND CONFORMATION OF BROMOMETHYL CYCLOPROPANE

被引：17

作者：

MOHAMMADI, MA

BROOKS, WVF

机构：

[1] Department of Chemistry, University of New Brunswick, Fredericton, NB E3B 5A3

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1979年 / 77卷 / 01期

关键词：

D O I：

10.1016/0022-2852(79)90194-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The microwave spectrum of gaseous bromomethyl cyclopropane (CH2CH2CHCH2Br) is reported in the range 12 to 36 GHz. Lines of the 79Br and 81Br species of cis and gauche forms are assigned and partial r0-structures derived. The rotational constants in MHz are: gauche C3H5CH279Br, A = 11 469.285, B = 1 374.777, C = 1 295.394; gauche C3H5CH281Br, A = 11 400.100, B = 1 364.088, C = 1 283.952; cis C3H5CH279Br, A = 8 759.918, B = 1 597.413, C = 1 522.141; cis C3H5CH281Br, A = 8 716.552, B = 1 583.761, C = 1 509.017. © 1979.

引用

页码：42 / 47

页数：6

共 10 条

[1] FREE-ENERGY OF CONFORMATIONAL-CHANGES IN VAPORS FROM LOW RESOLUTION MICROWAVE SPECTROSCOPIC INTENSITIES [J].