REACTIVITY OF PYRIDINECARBOXYLATE COMPLEXES OF RHODIUM(I) TOWARDS HG(OOCCF3)2 AND HG(PH)(OOCCF3) - CRYSTAL-STRUCTURE OF RH(C10H6NO2)(OOCCF3)2(H2O)[P(4-CH3-C6H4)3] .3.

被引：10

作者：

CANO, M

HERAS, JV

LOBO, MA

MARTINEZ, M

PINILLA, E

GUTIERREZ, E

MONGE, MA

机构：

[1] UNIV COMPLUTENSE MADRID,FAC CC QUIM,DIFRACC RAYOS LAB X,MADRID 3,SPAIN

[2] CSIC,INST MAT,MADRID 6,SPAIN

来源：

POLYHEDRON | 1991年 / 10卷 / 02期

关键词：

D O I：

10.1016/S0277-5387(00)81588-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of Rh(N-O)(CO)[P(4-X-C6H4)3][(N-O) = 2-C5NH4COO(pyC) and 2-C9NH6COO (quin), X = CH3O, CH3, F, Cl] with Hg(R)(OOCCF3) (R = Ph, OOCCF3) lead to the hexacoordinate rhodium(III), Rh(HgR)(OOCCF3)(N-O)(CO)[P(4-X-C6H4)3], complexes. The new compounds evolve in solution to the decarbonylated species Rh(R)(OOCCF3)(N-O)(H2O)[P(4-X6-C6H4)3]. The crystal of one of the above derivatives, Rh(OOCCF3)2(quin)(H2O)[P(4-CH3-C6H4)3], is reported, and a distorted octahedral coordination around the rhodium atom with the two monodentate OOCCF3 ligands in cis positions is found.

引用

页码：187 / 196

页数：10

共 19 条

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