IONIZATION OF PCL6- IN THE SOLID-STATE UNDER PRESSURE .1. PHASE-DIAGRAM OF PHOSPHORUS-PENTACHLORIDE

被引：14

作者：

CAHAY, R ^{[1
]}

WHALLEY, E ^{[1
]}

机构：

[1] NATL RES COUNCIL CANADA,DIV CHEM,OTTAWA K1A 0R9,ONTARIO,CANADA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 70卷 / 12期

关键词：

D O I：

10.1063/1.437425

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It is suggested that the PCl6 ion should ionize to PCl 4- and 2Cl in the solid under pressure, and evidence has been sought by measuring the phase diagram of phosphorus pentachloride, which has the constitution PCl4+PCl6-. Two new phases were discovered, one of which is wholly metastable relative to the ordinary phase. © 1979 American Institute of Physics.

引用

页码：5534 / 5538

页数：5

共 34 条

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