SYNTHESIS OF [M(ETA(2)-C2PH2)(CO)(P(I)PR3)2] (M=OS OR RU) AND X-RAY CRYSTAL-STRUCTURE OF THE OSMIUM DERIVATIVE

被引：20

作者：

ESPUELAS, J ^{[1
]}

ESTERUELAS, MA ^{[1
]}

LAHOZ, FJ ^{[1
]}

LOPEZ, AM ^{[1
]}

ORO, LA ^{[1
]}

VALERO, C ^{[1
]}

机构：

[1] UNIV ZARAGOZA, CSIC, INST CIENCIA MAT ARAGON, DEPT QUIM INORGAN, E-50009 ZARAGOZA, SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 468卷 / 1-2期

关键词：

RUTHENIUM; OSMIUM;

D O I：

10.1016/0022-328X(94)80053-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tetrahydrido complex [OsH4(CO)(PiPr3)2] (1) reacts with diphenylacetylene to give cis- and trans-stilbene and [Os(eta2-C2Ph2)(CO)(PiPr3)2] (5). The X-ray crystal structure of 5 has been determined. 5 reacts with CO to give [Os(eta2-C2Ph2)(CO)2(PiPr3)2](6). The related ruthenium complex [Ru(eta2-C2Ph2)(CO)(PiPr3)2](7) was obtained by reaction of [RuH(eta2-H2BH2)(CO)PiPr3)2] (8) with diphenylacetylene. 7 reacts with CO to give [Ru(CO)3(PiPr3)2] (9) and diphenylacetylene. The synthesis of the hydridovinyl complex [OsH(C(COOEt)=C(H)CO2Et)(CO)(P(i)Pr3)2] (10) is also reported.

引用

页码：223 / 228

页数：6

共 19 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS
ALLEN, FH
KENNARD, O
WATSON, DG
BRAMMER, L
ORPEN, AG
TAYLOR, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12): : S1 - S19
[2] KINETIC AND MECHANISTIC INVESTIGATION OF THE SEQUENTIAL HYDROGENATION OF PHENYLACETYLENE CATALYZED BY OSHCL(CO) (PME-TERT-BU2)2, OSHCL(CO)(P-I-PR3)2
ANDRIOLLO, A
ESTERUELAS, MA
MEYER, U
ORO, LA
SANCHEZDELGADO, RA
SOLA, E
VALERO, C
WERNER, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (19) : 7431 - 7437
[3] SYNTHESIS, REACTIVITY, MOLECULAR-STRUCTURE, AND CATALYTIC ACTIVITY OF THE NOVEL DICHLORODIHYDRIDOOSMIUM(IV) COMPLEXES OSH2CL2(P-I-PR3) OSH2CL2(PME-TERT-BU2)
ARACAMA, M
ESTERUELAS, MA
LAHOZ, FJ
LOPEZ, JA
MEYER, U
ORO, LA
WERNER, H
[J]. INORGANIC CHEMISTRY, 1991, 30 (02) : 288 - 293
[4] SYNTHESIS AND COMPARATIVE-STUDY OF IRON TRIAD M(CO)4(ETA-2-ALKYNE) COMPLEXES (M = FE, RU, OS ALKYNE = BIS(TRIMETHYLSILYL)ACETYLENE)
BALL, RG
BURKE, MR
TAKATS, J
[J]. ORGANOMETALLICS, 1987, 6 (09) : 1918 - 1924
[5] CAPELLE B, 1982, J CHEM SOC CHEM COMM, P567
[6] Cromer D.T, 1974, INT TABLES XRAY CRYS, VIV
[7] REACTIVITY OF OSH4(CO)(PIPR3)2 TOWARD TERMINAL ALKYNES - SYNTHESIS AND REACTIONS OF THE ALKYNYL-DIHYDROGEN COMPLEXES OSH(C2R)(ETA-2-H2)(CO)(PIPR3)2 (R = PH, SIME3)
ESPUELAS, J
ESTERUELAS, MA
LAHOZ, FJ
ORO, LA
VALERO, C
[J]. ORGANOMETALLICS, 1993, 12 (03) : 663 - 670
[8] REACTIVITY OF MH(ETA-2-H2BH2)(CO)(PIPR3)2 (M = OS, RU) TOWARD ELECTROPHILES - SYNTHESIS OF NEW HYDRIDOCARBONYLOSMIUM(II) AND RUTHENIUM(II) COMPLEXES CONTAINING TRIISOPROPYLPHOSPHINE AS LIGAND
ESTERUELAS, MA
GARCIA, MP
LOPEZ, AM
ORO, LA
RUIZ, N
SCHLUNKEN, C
VALERO, C
WERNER, H
[J]. INORGANIC CHEMISTRY, 1992, 31 (26) : 5580 - 5587
[9] HYDROSILYLATION OF PHENYLACETYLENE VIA AN OS(SIET3)(ETA-2-H2) INTERMEDIATE CATALYZED BY OSHCL(CO)(P(ISO-PR)3)2
ESTERUELAS, MA
ORO, LA
VALERO, C
[J]. ORGANOMETALLICS, 1991, 10 (02) : 462 - 466
[10] SYNTHESIS, MOLECULAR-STRUCTURE, AND REACTIVITY OF OCTAHEDRAL ALKYLHYDRIDOOSMIUM(II) COMPLEXES [OSH(R)(CO)2(PR'3)2]
ESTERUELAS, MA
LAHOZ, FJ
LOPEZ, JA
ORO, LA
SCHLUNKEN, C
VALERO, C
WERNER, H
[J]. ORGANOMETALLICS, 1992, 11 (06) : 2034 - 2043

← 1 2 →