PHOTOELECTRON-SPECTROSCOPY OF (C6F6)N- AND (AU-C6F6)- CLUSTERS

被引：119

作者：

NAKAJIMA, A

TAGUWA, T

HOSHINO, K

SUGIOKA, T

NAGANUMA, T

ONO, F

WATANABE, K

NAKAO, K

KONISHI, Y

KISHI, R

KAYA, K

机构：

[1] INST PHYS & CHEM RES, WAKO, SAITAMA 35101, JAPAN

[2] KEIO UNIV, FAC SCI & TECHNOL, DEPT CHEM, KOHOKU KU, YOKOHAMA, KANAGAWA 223, JAPAN

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 214卷 / 01期

关键词：

D O I：

10.1016/0009-2614(93)85449-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photoelectron spectra of hexafluorobenzene (C6F6) cluster anions and its Au complex anion were measured in the gas phase at the photon energy of 3.49 eV, using a magnetic bottle electron spectrometer having almost-equal-to 80 meV resolution. The spectra show unresolved broad features: The vertical detachment energies (VDEs) were determined from the maxima of the spectra. The VDE of (C6F6)n- gradually increases by 0.1-0.2 eV with the cluster size (n = 1-8) from 1.56 (3) to 2.54 (6) eV, and the VDE of (Au-C6F6)- anion is 1.99 (5) eV.

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页码：22 / 26

页数：5

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