ELECTRONIC-SPECTRUM OF JET-COOLED 9-HYDROXYPHENALENONE-D - VIBRATIONAL-MODE SPECIFIC PROTON TUNNELING IN THE S-0 STATE

被引：14

作者：

SEKIYA, H ^{[1
]}

NAKANO, N ^{[1
]}

NISHI, K ^{[1
]}

HAMABE, H ^{[1
]}

SAWADA, T ^{[1
]}

TASHIRO, M ^{[1
]}

NISHIMURA, Y ^{[1
]}

机构：

[1] KYUSHU UNIV, GRAD SCH ENGN SCI, DEPT MOLEC SCI & TECHNOL, KASUGA, FUKUOKA 816, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 10期

关键词：

D O I：

10.1246/cl.1995.893

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The fluorescence excitation and dispersed fluorescence of jet-cooled 9-hydroxyphenalenone-d have been measured to investigate vibrational mode specific proton tunneling in the S-0 state. Tunneling splittings of a few vibrationally excited states have been determined.

引用

页码：893 / 894

页数：2

共 11 条

[1]

BONDYBEY VE, 1984, J CHEM PHYS, V80, P5432, DOI 10.1063/1.446650

[2]

HADDON RC, 1980, MOL ELECTRONIC DEVIC, pCH2

[3]

HADDON RC, 1986, J ORG CHEM, V46, P4588

[4] DIELECTRIC-RELAXATION DERIVED FROM COLLECTIVE MOLECULAR-REORIENTATION OF 9-HYDROXYPHENALENONE IN THE SOLID SATE [J].

MOCHIDA, T ;

IZUOKA, A ;

SUGAWARA, T ;

MORITOMO, Y ;

TOKURA, Y .

JOURNAL OF CHEMICAL PHYSICS, 1994, 100 (09) :6646-6648

[5] THE ROLE OF ELECTRONIC AND GEOMETRIC FACTORS IN PROTON TUNNELING - A COMPARATIVE-STUDY OF TROPOLONE AND 9-HYDROXYPHENALENONE BY THRESHOLD PHOTOELECTRON-SPECTROSCOPY [J].

OZEKI, H ;

TAKAHASHI, M ;

OKUYAMA, K ;

KIMURA, K .

JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (01) :56-66

[6] INTRAMOLECULAR PROTON TUNNELLING IN THE GROUND AND LOWEST EXCITED SINGLET-STATES OF 9-HYDROXYPHENALENONE [J].

ROSSETTI, R ;

HADDON, RC ;

BRUS, LE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (23) :6913-6916

[7] VIBRATIONAL MODE-SPECIFIC TUNNELING SPLITTINGS IN THE APPROXIMATELY-A STATES OF DEUTERATED TROPOLONES [J].

SEKIYA, H ;

NAGASHIMA, Y ;

TSUJI, T ;

NISHIMURA, Y ;

MORI, A ;

TAKESHITA, H .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (25) :10311-10317

[8] ELECTRONIC-SPECTRA OF JET-COOLED TROPOLONE - EFFECT OF THE VIBRATIONAL-EXCITATION ON THE PROTON TUNNELING DYNAMICS [J].

SEKIYA, H ;

NAGASHIMA, Y ;

NISHIMURA, Y .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (10) :5761-5769

[9]

SEKIYA H, IN PRESS

[10] EFFECTS OF VIBRATIONAL-EXCITATION ON MULTIDIMENSIONAL TUNNELING - GENERAL STUDY AND PROTON TUNNELING IN TROPOLONE [J].

TAKADA, S ;

NAKAMURA, H .

JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (10) :3977-3992

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