CARBON-DIOXIDE SENSOR USING SOLID ELECTROLYTES WITH ZIRCONIUM-PHOSPHATE FRAMEWORK

被引：29

作者：

IKEDA, S ^{[1
]}

KATO, S ^{[1
]}

NOMURA, K ^{[1
]}

ITO, K ^{[1
]}

EINAGA, H ^{[1
]}

SAITO, S ^{[1
]}

FUJITA, Y ^{[1
]}

机构：

[1] JAPAN STORAGE BATTERY CO LTD,CTR CORP RES & DEV,MINAMI KU,KYOTO 601,JAPAN

来源：

SOLID STATE IONICS | 1994年 / 70卷 / pt 1期

关键词：

D O I：

10.1016/0167-2738(94)90374-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We adopted divalent cationic conductor, MgZr4(PO4)6(MgZP), for the first time as the electrolyte of EMF type CO2 gas sensors, having the following cell construction: Pt\CO2, O2\ metal carbonate parallel-to solid electrolyte \O-2, Pt. In the case of sodium carbonate (Na2CO3), the sensor showed the Nernstian response to CO2 in pressure range between 1 and 100 KPa at temperatures from 400 to 500-degrees-C within a few minutes.

引用

页码：569 / 571

页数：3

共 6 条

[1] SOLID ELECTROLYTES WITH MULTIVALENT CATION CONDUCTION .1. CONDUCTING SPECIES IN MG-ZR-PO4 SYSTEM [J].

IKEDA, S ;

TAKAHASHI, M ;

ISHIKAWA, J ;

ITO, K .

SOLID STATE IONICS, 1987, 23 (1-2) :125-129

[2] SOLID ELECTROLYTES WITH MULTIVALENT CATION CONDUCTION .2. ZINC ION CONDUCTION IN ZN-ZR-PO4 SYSTEM [J].

IKEDA, S ;

KANBAYASHI, Y ;

NOMURA, K ;

KASAI, A ;

ITO, K .

SOLID STATE IONICS, 1990, 40-1 :79-82

[3] FRAMEWORK STRUCTURE, PHASE-TRANSITION, AND TRANSPORT-PROPERTIES IN MIIZR4(PO4)6 COMPOUNDS (MII=MG, CA, SR, BA, MN, CO, NI, ZN, CD, AND PB) [J].

NOMURA, K ;

IKEDA, S ;

ITO, K ;

EINAGA, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (12) :3221-3227

[4] IONIC-CONDUCTION BEHAVIOR IN ZIRCONIUM-PHOSPHATE FRAMEWORK [J].

NOMURA, K ;

IKEDA, S ;

ITO, K ;

EINAGA, H .

SOLID STATE IONICS, 1993, 61 (04) :293-301

[5] SOLID ELECTROLYTE CO2 SENSOR USING BINARY CARBONATE ELECTRODE [J].

YAO, S ;

SHIMIZU, Y ;

MIURA, N ;

YAMAZOE, N .

CHEMISTRY LETTERS, 1990, (11) :2033-2036

[6]

1961, GMELINS HDB ANORGA B, V3, P1338

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