THE PYROLYSIS OF BUTATRIENONE PRECURSORS - 3,4-DIAZATRICYCLO[5.2.1.0/2,6]DECA-3,8-DIENE-ENDO-CIS-2,6-DICARBOXYLIC ANHYDRIDE AND ITS 5,5-DIPHENYL DERIVATIVE

被引：3

作者：

ANDERSON, MR

BROWN, RFC

BROWNE, NR

EASTWOOD, FW

FALLON, GD

GAN, DPC

PULLIN, ADE

STAFFA, AC

机构：

[1] Department of Chemistry, Monash University, Clayton, VIC

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1990年 / 43卷 / 03期

关键词：

D O I：

10.1071/CH9900549

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Flash vacuum pyrolysis of the title anhydride (4) gave a poor yield of butatrienone, detected by argon matrix isolation infrared spectroscopy. Similar pyrolysis of the 5, 5-diphenyl derivative (8) failed to give diphenylbutatrienone; the red product (16) is considered to have been formed by dimerization of an intermediate 2 H-indenylidenemethanone (15). The crystal structure of (16) has been determined. © 1990 ASEG.

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页码：549 / 560

页数：12

相关论文

共 11 条

[1] GENERATION OF BUTATRIENONE (VINYLIDENEKETENE) BY FLASH VACUUM PYROLYSIS AND MEASUREMENT OF ITS MICROWAVE-SPECTRUM [J].

BROWN, RD ;

BROWN, RFC ;

EASTWOOD, FW ;

GODFREY, PD ;

MCNAUGHTON, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (16) :4705-4708

[2] SYNTHESIS OF PRECURSORS OF C4-CUMULENONE AND C5-CUMULENONE [J].

BROWN, RFC ;

COULSTON, KJ ;

EASTWOOD, FW ;

GATEHOUSE, BM ;

GUDDATT, LW ;

PFENNINGER, M ;

RAINBOW, I .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1984, 37 (12) :2509-2524

[3] ARGON MATRIX STUDY OF THE INFRARED-SPECTRUM OF BUTATRIENONE [J].

BROWN, RFC ;

COULSTON, KJ ;

EASTWOOD, FW ;

PULLIN, ADE ;

STAFFA, AC .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1990, 43 (03) :561-577

[4]

Diels O, 1931, LIEBIGS ANN CHEM, V490, P236

[5] BICYCLO[2.2.1]HEPTA-2,5-DIENE-2,3-DICARBOXYLIC ANHYDRIDE [J].

EDMAN, JR ;

SIMMONS, HE .

JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (10) :3808-&

[6] CRYSTAL-STRUCTURES OF SOME NIOBIUM AND TANTALUM OXIDES .8. THE 5RB2O-14.6TA2O5 PHASE - A TUNNEL STRUCTURE [J].

FALLON, GD ;

GATEHOUSE, BM .

JOURNAL OF SOLID STATE CHEMISTRY, 1980, 34 (02) :193-198

[7]

Ibers J. A., 1974, INT TABLES XRAY CRYS, VIV

[8] CHEMISTRY OF THE CUMULENES .5. WITTIG REACTION WITH CARBON SUBOXIDE - SYNTHESIS OF DIMETHYL 1,5-DIPHENYL-1,2,3,4-PENTATETRAENEDICARBOXYLATE [J].

NADER, FW ;

BRECHT, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (01) :93-94

[9] HYDROPHOBIC ACCELERATION OF DIELS-ALDER REACTIONS [J].

RIDEOUT, DC ;

BRESLOW, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (26) :7816-7817

[10]

SHELDRICK GM, 1975, SHELX PROGRAM CRYSTA