PALLADIUM CATALYZED DIRECT OXIDATION OF BENZENE WITH MOLECULAR-OXYGEN TO PHENOL

被引：61

作者：

JINTOKU, T

TAKAKI, K

FUJIWARA, Y

FUCHITA, Y

HIRAKI, K

机构：

[1] IDEMITSU PETROCHEM CO LTD, TOKUYAMA 745, JAPAN

[2] NAGASAKI UNIV, FAC ENGN, DEPT IND CHEM, NAGASAKI 852, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 02期

关键词：

D O I：

10.1246/bcsj.63.438

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct phenol synthesis from benzene is currently one of the most important problems in modern chemistry. We have reported new phenol synthesis from benzene and O2 via direct activation of a C-H aromatic bond by the Pd(OAc)2/phenanthroline catalyst system. The evidence for direct oxidation of benzene by O2 was obtained using 18O and 2H isotopes. The mechanism was proposed on the basis of these results and the reactions of Ph-Pd σ complex intermediates.

引用

页码：438 / 441

页数：4

共 16 条

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