Z-]E PHOTOISOMERIZATION OF HOMOACTIVATED CARBON CARBON DOUBLE-BONDS

被引：6

作者：

KALTIA, S

MATIKAINEN, J

HASE, T

机构：

[1] Division of Organic Chemistry, Department of Chemistry, University of Helsinki, Vuorikatu 20

来源：

SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 8-9期

关键词：

D O I：

10.1080/00397919108019798

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Z-configured 1,4-diene or beta,gamma-unsaturated carbonyl systems are readily available by the Wittig reaction. Isomerization required for access into the E-series can easily be accomplished by irradiation using an ordinary tungsten lamp and diphenyl disulphide sensitizer. There is very little formatation of conjugated isomers (less than 1%).

引用

页码：1083 / 1086

页数：4

共 5 条

[1] TOTAL SYNTHESIS OF HUMULENE [J].