DIOXIRANES .20. PREPARATION AND PROPERTIES OF SOME NEW DIOXIRANES

被引：68

作者：

MURRAY, RW

SINGH, M

JEYARAMAN, R

机构：

[1] Department of Chemistry, University of Missouri, St. Louis

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 04期

关键词：

D O I：

10.1021/ja00030a032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The in situ method for producing dioxiranes has been modified to permit the isolation in ketone solution of some nonvolatile dioxiranes. The dioxiranes have been characterized spectroscopically and, in some cases, by chemical reactions.

引用

页码：1346 / 1351

页数：6

共 44 条

[1] SPECTRAL AND CHEMICAL-PROPERTIES OF DIMETHYLDIOXIRANE AS DETERMINED BY EXPERIMENT AND ABINITIO CALCULATIONS [J].

ADAM, W ;

CHAN, YY ;

CREMER, D ;

GAUSS, J ;

SCHEUTZOW, D ;

SCHINDLER, M .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (13) :2800-2803

[2] DIOXIRANES - A NEW CLASS OF POWERFUL OXIDANTS [J].

ADAM, W ;

CURCI, R ;

EDWARDS, JO .

ACCOUNTS OF CHEMICAL RESEARCH, 1989, 22 (06) :205-211

[3]

BAEYER A, 1989, BER DTSCH CHEM GES, V32, P3625

[4] EPOXIDATION BY DIMETHYLDIOXIRANE - ELECTRONIC AND STERIC EFFECTS [J].

BAUMSTARK, AL ;

VASQUEZ, PC .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (15) :3437-3439

[5] EPOXIDATION OF ALKENES BY DIMETHYLDIOXIRANE - EVIDENCE FOR A SPIRO TRANSITION-STATE [J].

BAUMSTARK, AL ;

MCCLOSKEY, CJ .

TETRAHEDRON LETTERS, 1987, 28 (29) :3311-3314

[6] CYCLOPENTADIENONE O-OXIDE - A HIGHLY LABILE INTERMEDIATE IN THE MATRIX REACTION BETWEEN CYCLOPENTADIENYLIDENE AND OXYGEN [J].

BELL, GA ;

DUNKIN, IR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (21) :1213-1215

[7]

BRODE GL, 1973, POLYM HETEROCYCLICS, P117

[8] ON THE MECHANISM OF THE BAEYER-VILLIGER OXIDATION OF KETONES BY BIS(TRIMETHYLSILYL) PEROXOMONOSULFATE - INTERMEDIACY OF DIOXIRANES [J].

CAMPOREALE, M ;

FIORANI, T ;

TROISI, L ;

ADAM, W ;

CURCI, R ;

EDWARDS, JO .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (01) :93-98

[9] O-17 AND C-13 IDENTIFICATION OF THE DIMETHYLDIOXIRANE INTERMEDIATE ARISING IN THE REACTION OF POTASSIUM CARBONATE WITH ACETONE [J].

CASSIDEI, L ;

FIORENTINO, M ;

MELLO, R ;

SCIACOVELLI, O ;

CURCI, R .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (04) :699-700

[10] CYCLOPENTADIENONE O-OXIDE - SPECTROSCOPIC OBSERVATION AND PHOTOCHEMISTRY OF A CARBONYL OXIDE [J].

CHAPMAN, OL ;

HESS, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (06) :1842-1843

← 1 2 3 4 5 →