TRANSIENT SPECIES OF IMPORTANCE IN STOICHIOMETRIC HYDROFORMYLATION REACTION .1. EVIDENCE FOR HCO(CO)3 BY MATRIX-ISOLATION

被引：37

作者：

WERMER, P

AULT, BS

ORCHIN, M

机构：

[1] Department of Chemistry, University of Cincinnati, Cincinnati

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1978年 / 162卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)82037-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Spectra of HCo(CO)4 in a low temperature argon matrix show a weak band at 2018 cm-1. On irradiation, this band grows rapidly and additional bands (previously too weak to be readily observable) appear at 2025 and 485 cm-1. These three bands are assigned to HCo(CO)3, a coordinatively unsaturated species persistently proposed as an intermediate in the hydroformylation reaction but not previously characterized. © 1978.

引用

页码：189 / 194

页数：6

共 16 条

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