SYNTHESIS AND EXCHANGE-REACTIONS OF 1,4,8,11-TETRAAZACYCLOTETRADECA-7(E),14(E)-DIENE-5,12-DIONES

被引：20

作者：

HEGEDUS, LS

MOSER, WH

机构：

[1] Department of Chemistry, Colorado State University, Colorado 80523, Fort Collins

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 25期

关键词：

D O I：

10.1021/jo00104a039

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A number of functionalized, unsaturated 5,12-dioxo cyclams were synthesized by acid-catalyzed dimerization of appropriately functionalized azapenams. Although easily isolated and purified, these unsaturated tetraaza macrocycles underwent acid-catalyzed exchange reactions of the monomer unit to give mixed systems. Even a simple dihydrobenzazepine participated in this exchange process to give a ''hybrid'' macrocycle.

引用

页码：7779 / 7784

页数：6

共 20 条

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