THE CYCLING BEHAVIOR AND CAPACITY DETERIORATION MODEL OF HYDRIDE ELECTRODES IN CHARGING-DISCHARGING CYCLING

被引：2

作者：

LI, ZP

LEI, YQ

LIU, BH

WU, J

WANG, QD

机构：

[1] Department of Materials Science and Engineering, Zhejiang University, Hangzhou

来源：

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 1994年 / 183卷

关键词：

HYDRIDE ELECTRODE; CAPACITY DEGRADATION; HYDROXIDE FORMATION; ACTIVATION PROCESS; CYCLING BEHAVIOR;

D O I：

10.1524/zpch.1994.183.Part_1_2.287

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this paper, a relation between the electrochemical capacity of a rare-earth based hydride electrode and cycling number is deduced on the basis of formation of rare-earth hydroxide. Experimental data are in good agreement with the deduced relation. The parameters of k and f of some hydride electrodes are calculated on the basis of the relation.

引用

页码：287 / 295

页数：9

共 8 条

[1] Kinetics of phase change I - General theory
Avrami, M
[J]. JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12) : 1103 - 1112
[2] Avrami M., 1940, J CHEM PHYS, V8, P212, DOI DOI 10.1063/1.1750631
[3] THE INFLUENCE OF THE PRETREATMENT OF POWDER ON THE RESULTING PROPERTIES OF LANI5 ELECTRODES
BOONSTRA, AH
BERNARDS, TMN
[J]. JOURNAL OF THE LESS-COMMON METALS, 1990, 161 (02): : 245 - 255
[4] THE CYCLING BEHAVIOR OF MISCH METAL NICKEL-BASED METAL HYDRIDE ELECTRODES AND THE EFFECTS OF COPPER PLATING ON THEIR PERFORMANCE
LEI, YQ
LI, ZP
CHEN, CP
WU, J
WANG, QD
[J]. JOURNAL OF THE LESS-COMMON METALS, 1991, 172 : 1265 - 1272
[5] RARE-EARTH-BASED ALLOY ELECTRODES FOR A NICKEL METAL HYDRIDE BATTERY
SAKAI, T
HAZAMA, T
MIYAMURA, H
KURIYAMA, N
KATO, A
ISHIKAWA, H
[J]. JOURNAL OF THE LESS-COMMON METALS, 1991, 172 : 1175 - 1184
[6] SCHLAPBACH L, 1974, INT J HYDROGEN ENERG, V4, P21
[7] CAPACITIES AND DURABILITIES OF TI-ZR-NI ALLOY HYDRIDE ELECTRODES AND EFFECTS OF ELECTROLESS PLATING ON THEIR PERFORMANCES
WAKAO, S
SAWA, H
NAKANO, H
CHUBACHI, S
ABE, M
[J]. JOURNAL OF THE LESS-COMMON METALS, 1987, 131 : 311 - 319
[8] Willems J. J. G., 1984, Philips Journal of Research, V39, P1

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