A CHIRAL SCANDIUM CATALYST FOR ENANTIOSELECTIVE DIELS-ALDER REACTIONS

被引：109

作者：

KOBAYASHI, S

ARAKI, M

HACHIYA, I

机构：

[1] Department of Applied Chemistry, Faculty of Science, Science University of Tokyo (SUT), Tokyo 162, Kagurazaka, Shinjuku-ku

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 14期

关键词：

D O I：

10.1021/jo00093a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A chiral scandium catalyst, prepared from scandium trifluoromethanesulfonate (Sc(OTf)(3)), (R)-(+)1,1'-bi-2-naphthol, and a tertiary amine in dichloromethane, was quite effective in the enantioselective Diels-Alder reactions of acyl-1,3-oxazolidin-2-ones with dienes, and the corresponding Diels-Alder adducts were obtained in high yields with high diastereo- and enantioselectivities.

引用

页码：3758 / 3759

页数：2

共 18 条

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