SYNTHESIS AND CHARACTERIZATION OF SOME NEW DIAZOPEPTIDES

被引：7

作者：

CHALLIS, BC ^{[1
]}

LATIF, F ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,LONDON SW7 2AZ,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 04期

关键词：

D O I：

10.1039/p19900001005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of eight new diazopeptides by aprotic diazotisation with N2O4 is described for glycyl-glycine, triglycine, pentaglycine, L-leucylglycine and the ethyl esters of L-leucylglycine, L-alanylglycine, L-serylglycine and L-threonylglycine. The diazo derivatives (7)-(10) of the parent peptides are isolated as calcium salts. The UV-vis., IR, 1H NMR and MS properties of the new diazopeptides are reported together with those for the diazo derivative of glycylglycine ethyl ester and glycylglycinamide.

引用

页码：1005 / 1009

页数：5

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