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SYNTHESIS AND ELECTROCHEMISTRY OF CROWN-ETHER DITHIOLENE COMPLEXES

被引：37
作者：
GREEN, MLH
HEUER, WB
SAUNDERS, GC
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1990年 / 12期
关键词：
D O I：
10.1039/dt9900003789
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The syntheses of copper and bis(eta-cyclopentadienyl)molybdenum complexes of a dithiolene ligand incorporating a trioxadithia-15-crown-5-unit [1,4,7-trioxa-10, 13-dithiacyclopentadec-11-ene-11, 12-dithiolate(2-)] are described. The electrochemistry of these complexes was investigated by cyclic voltammetry in acetonitrile. Upon addition of an excess of alkali-metal cations large shifts of the redox potentials of the compounds were observed.
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页码：3789 / 3792
页数：4
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