A SIMPLIFIED, HIGH-YIELD SYNTHESIS, AND CRYSTAL-STRUCTURE OF [TRIS(BIS(2,4,6-TRIISOPROPYLPHENYL)TIN)]

被引：9

作者：

BRADY, FJ ^{[1
]}

CARDIN, CJ ^{[1
]}

CARDIN, DJ ^{[1
]}

CONVERY, MA ^{[1
]}

DEVEREUX, MM ^{[1
]}

LAWLESS, GA ^{[1
]}

机构：

[1] UNIV DUBLIN TRINITY COLL,DEPT CHEM,DUBLIN 2,IRELAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 421卷 / 2-3期

关键词：

D O I：

10.1016/0022-328X(91)86404-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The species [{Sn(C6H2iPr3-2,4,6)2}3] has been obtained in a simple, essentially quantitative, synthesis from SnCl2 and ArLi in diethyl ether at low temperature. The crystal structure analysis confirms the trimeric nature of the molecular units but reveals some unusual features. The crystal contains the unusual feature of an asymmetric unit that consists of three units of [{SnAr2}3] in P2(1)/c; the molecular unit is a scalene triangle, showing high consistency between the three molecules, in contrast to analogous trimeric species of silicon or germanium. The Sn-Sn bonds are lengthened (average value 2.942 angstrom) owing to steric crowding.

引用

页码：199 / 203

页数：5

共 4 条

[1] CYCLOTRISTANNOXANE (R2SNO)3 AND CYCLOTRISTANNANE (R2SN)3 SYSTEMS - SYNTHESIS AND CRYSTAL-STRUCTURES [J].