FUNCTIONALLY SUBSTITUTED MONOCYCLOPENTADIENYL COMPOUNDS - FORMATION OF [NI(ETA-CH3C5H4)(X)(PPH3)] AND DERIVATIVES WITH OTHER PHOSPHINES - X-RAY CRYSTAL-STRUCTURE OF [NI(ETA-CH3C5H4)(I)(PPH3)]

被引：10

作者：

BALLESTER, L ^{[1
]}

PEREZ, S ^{[1
]}

GUTIERREZ, A ^{[1
]}

PERPINAN, MF ^{[1
]}

GUTIERREZPUEBLA, E ^{[1
]}

MONGE, A ^{[1
]}

RUIZ, C ^{[1
]}

机构：

[1] UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,DIFRACC RAYOS X LAB,E-28040 MADRID,SPAIN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 414卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86339-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Ni(eta-CH3C5H4)2] reacts with [NiX2(PPh3)2] (X = Cl, Br, I, CN, SCN) to give monocyclopentadienyl complexes. The reactions of these complexes with tertiary phosphines or carbon monoxide are described. The crystal structure of [Ni(eta-CH3C5H4)(I)(PPh3)] has been determined, and shows the nickel atom to be in a pseudo-pentacoordinate environment.

引用

页码：411 / 420

页数：10

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