CATALYTIC ASYMMETRIC C-C BOND FORMATION - NEW ENOLATOLITHIUM AND ORGANOLITHIUM CHEMISTRY

被引：26

作者：

BERRISFORD, DJ

机构：

[1] Department of Chemistry, University of Manchester, Institute of Science, Manchester, M60 1QD

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 02期

关键词：

ASYMMETRIC SYNTHESIS; CATALYSIS; LITHIUM COMPOUNDS;

D O I：

10.1002/anie.199501781

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic and enantioselective are two new efficient processes for CC bond formation developed from fundamental reactions of organolithium compounds. Koga et al. have achieved the benzylation of Li enolates in the presence of both chiral (L*) and achiral (L) ligands [Eq.(a)], and Denmark et al. describe the addition of RLi to aryl imines [Eq. (b)] with very good selectivities, R  Me, vinyl. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：178 / 180

页数：3

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