ELECTROPHILIC AROMATIC SUBSTITUTION .3. NITRATION AND ACIDCATALYSED HYDROLYSIS OF BENZYLIDYNE TRIFLUORIDE

被引：9

作者：

COOMBES, RG

MOODIE, RB

SCHOFIEL.K

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 01期

关键词：

D O I：

10.1039/j29690000052

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The partial rate factor for the meta-nitration of benzylidyne trifluoride by nitric acid in sulphuric acid is 6.7 × 10-5. Evidence is presented to support a mechanism for the hydrolysis of benzylidyne trifluoride to form benzoic acid in concentrated sulphuric acid which involves a transition state similar in structure to the carbonium ion PhCF2+.

引用

页码：52 / &

共 10 条

[1]

ALBERS RJ, 1964, RECL TRAV CHIM PAY B, V83, P930

[2]

COOMBES RC, TO BE PUBLISHED

[3] ELECTROPHILIC AROMATIC SUBSTITUTION .I. NITRATION OF SOME REACTIVE AROMATIC COMPOUNDS IN CONCENTRATED SULPHURIC AND PERCHLORIC ACIDS [J].