MAGNETIC COUPLING AND H-1-NMR SPECTROSCOPY OF BINUCLEAR COPPER(II) COMPLEXES

被引：46

作者：

SATCHER, JH ^{[1
]}

BALCH, AL ^{[1
]}

机构：

[1] UNIV CALIF DAVIS,DEPT CHEM,DAVIS,CA 95616

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 13期

关键词：

D O I：

10.1021/ic00117a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

H-1 NMR spectra with narrow, well-resolved resonances are reported for a set of binuclear copper(II) complexes, [Cu-2(L-R)(X)](ClO4)(2). A quantitative relationship exists between the chemical shift of selected peaks and magnetic coupling between the paramagnetic centers over a wide range (2J = +26 to -1100 cm(-1)) of coupling constants. Such spectra are shown to be useful in assaying sample purity and in estimating magnetic coupling constants.

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页码：3371 / 3373

页数：3

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