OPTIMAL-CONTROL THEORY APPROACH TO ENHANCEMENT OF HGAR PHOTODISSOCIATION

被引：7

作者：

AMSTRUP, B

RICE, SA

机构：

[1] UNIV CHICAGO,JAMES FRANCK INST,CHICAGO,IL 60637

[2] TECH UNIV DENMARK,DEPT CHEM B,DK-2800 LYNGBY,DENMARK

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 225卷 / 1-3期

关键词：

D O I：

10.1016/0009-2614(94)00610-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Practical application of the Tannor-Rice scheme for selective photochemistry requires that the effects of changes in the laser temporal pulse shapes must be understood. We report the results of a study of the effects of pulse shaping, within the Tannor-Rice scheme, applied to a simple diatomic molecule, namely the van der Waals complex HgAr. Optimal control theory is used to generate pulse shapes which provide enhanced reaction yield. The best yields are found by the method of simulated annealing using Gaussian pulse shapes.

引用

页码：1 / 10

页数：10

共 27 条

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