CONCEPTUAL ERRORS IN THE THEORY OF FIELD ADSORPTION

被引：8

作者：

FORBES, RG

机构：

[1] University of Aston, Department of Physics, Birmingham, B4 7ET, Gosta Green

来源：

SURFACE SCIENCE | 1979年 / 87卷 / 01期

关键词：

D O I：

10.1016/0039-6028(79)90191-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Serious conceptual errors are shown to exist in a new theoretical treatment of field adsorption proposed by Tsong in a recent review. A conceptual error also exists in the standard approach, in that the influence of the adsorbate on the internal energy of the source of the electric field has been neglected. A numerical estimate of the size of the correction to the short-range field-adsorption binding energy, made by means of the isolated-dipole-pair approximation, shows that the correction is small but should not be neglected in detailed treatments. © 1979.

引用

页码：L278 / L284

页数：7

共 12 条

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[8]

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[10]

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