FORMATION OF AN ANCHORED COPPER(II) COMPLEX ON A THIOUREA-FUNCTIONALIZED SILICA-GEL BY IN-SITU MODIFICATION OF THE TETHERED LIGATING FUNCTION

被引：12

作者：

CAUZZI, D

PREDIERI, G

TIRIPICCHIO, A

ZANONI, R

GIORI, C

机构：

[1] UNIV PARMA,DIPARTIMENTO CHIM GEN & INORGAN CHIM ANALIT CHIM FIS,VIALE SCI,I-43100 PARMA,ITALY

[2] UNIV ROMA LA SAPIENZA,DIPARTIMENTO CHIM,I-00185 ROME,ITALY

[3] UNIV ROMA LA SAPIENZA,IST SCI FIS,I-00185 ROME,ITALY

来源：

INORGANICA CHIMICA ACTA | 1994年 / 221卷 / 1-2期

关键词：

COPPER COMPLEXES; ANCHORED COMPLEXES; THIOUREA-FUNCTIONALIZED XEROGELS;

D O I：

10.1016/0020-1693(94)03973-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper(II) chloride reacts with a double-thiourea ligand tethered on a silica xerogel through a reduction-oxidation process. XPS data suggest that the main products are copper(I) chloride supported on the matrix and a tethered copper(II) compound containing a heterocyclic ligand derived from the double thiourea by oxidative mono-desulfurization. The presence of this anchored complex is also substantiated by ESR measurements.

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页码：183 / 186

页数：4

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