A NEW SELECTIVE AND HIGH-AFFINITY POLYMERIC COMPLEXING AGENT FOR TRANSITION-METAL IONS

The synthesis and characteristics of a new chelating glycinohydroxamate-containing polymer resin is described. The functionality of the polymer is 1.76 mmol g-1. The hydrogen capacity, water regain and adsorption capacities for iron(III), cadmium(II), cobalt(II), copper(II), nickel(II) and zinc(II) were measured at various pH values; uptake of the metal ions increased with pH and was quantitative above pH 3 for most of the metal ions. All cations studied showed high exchange rates towards the resin. The half saturation times for iron(III), cadmium(II), copper(II) and zinc(II) were all less than 1 min. The coordination behaviour of the resin was studied with the help of e.p.r., i.r., u.v. and potentiometry. The pK(a) of the resin is 10.70 and the log value of the stability constants for iron(III), copper(II), lead(II), zinc(II), cobalt(II), manganese(II), cadmium(II) and nickel(II) were measured as 21.81, 19.50, 19.20, 18.59, 18.51, 18.46, 18.37 and 18.36, respectively, at 25-degrees-C and I = 0.2 M KCl.