NEW CYCLOHEPTATRIENE AND CYCLOHEPTATRIENYL DERIVATIVES OF NIOBIUM

被引：9

作者：

GREEN, MLH ^{[1
]}

MOUNTFORD, P ^{[1
]}

SCOTT, P ^{[1
]}

MTETWA, VSB ^{[1
]}

机构：

[1] UNIV SWAZILAND,MANZINI,SWAZILAND

来源：

POLYHEDRON | 1991年 / 10卷 / 03期

关键词：

D O I：

10.1016/S0277-5387(00)80161-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The one-pot synthesis of [Nb(eta-6-C7H8)(PMe3)2Cl2] and [Nb(eta-C7H7)(eta-4-C7H8) (PMe3)] from [NbCl4(thf)2] (thf = tetrahydrofuran) have provided a convenient route to the virtually unexplored eta-cycloheptatrienyl niobium system. The X-ray crystal structures of the subsequent derivatives [Nb(eta-C7H7)(Me2PCH2CH2PMe2)CO] and 17-electron [Nb(eta-C7H7)(PMe3)2I] have been determined.

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页码：389 / 392

页数：4

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