MULTIDIMENSIONAL MOLECULAR-METALS WITH PI-ACCEPTOR M(DMIT)2 AND ANALOGOUS MOLECULES

被引：25

作者：

KOBAYASHI, H ^{[1
]}

KATO, R ^{[1
]}

KOBAYASHI, A ^{[1
]}

机构：

[1] UNIV TOKYO,FAC SCI,DEPT CHEM,TOKYO 113,JAPAN

来源：

SYNTHETIC METALS | 1991年 / 42卷 / 03期

关键词：

D O I：

10.1016/0379-6779(91)91411-3

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Crystal and electronic structures and resistivity of a new molecular metal C7H16N[Ni(dmit)2]2 were examined. Ni(dmit)2 molecules are arranged to form metal layers, with taking the "spanning overlapping mode". Extended Huckel band structure gave two-dimensional Fermi surface. The system is metallic at least down to 1.5 K. The synthesis of dmis (bis(2-selenone-1,3-dithiole-4,5-dithiolato)) ligand and the electrochemical data of Ni(dmis)2 are also reported.

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页码：2495 / 2498

页数：4

相关论文

共 10 条

[1]

BROSSARD L, 1988, SYNTHETIC MET, V27, pB157, DOI 10.1016/0379-6779(88)90139-7

[2]

BROSSARD L, 1986, CR ACAD SCI II, V302, P205

[3] CRYSTAL-STRUCTURE AND ELECTRICAL-CONDUCTIVITY OF (ET4N)0.5[NI(DMIT)2] [J].

KATO, R ;

MORI, T ;

KOBAYASHI, A ;

SASAKI, Y ;

KOBAYASHI, H .

CHEMISTRY LETTERS, 1984, (01) :1-4

[4] CRYSTAL AND ELECTRONIC-STRUCTURES OF A NEW TWO-DIMENSIONAL MOLECULAR-METAL, ALPHA-ET2ME2N[NI(DMIT)2]2 [J].

KATO, R ;

KOBAYASHI, H ;

KIM, H ;

KOBAYASHI, A ;

SASAKI, Y ;

MORI, T ;

INOKUCHI, H .

CHEMISTRY LETTERS, 1988, (05) :865-868

[5] THE 1ST MOLECULAR SUPERCONDUCTOR BASED ON PI-ACCEPTOR MOLECULES AND CLOSED-SHELL CATIONS, [(CH3)4N][NI(DMIT)2]2, LOW-TEMPERATURE X-RAY STUDIES AND SUPERCONDUCTING TRANSITION [J].

KOBAYASHI, A ;

KIM, H ;

SASAKI, Y ;

KATO, R ;

KOBAYASHI, H ;

MORIYAMA, S ;

NISHIO, Y ;

KAJITA, K ;

SASAKI, W .

CHEMISTRY LETTERS, 1987, (09) :1819-1822

[6] LAYERED MOLECULAR SUPERCONDUCTORS THETA-(BEDT-TTF)2I3 AND KAPPA-(BEDT-TTF)2I3 [J].

KOBAYASHI, H ;

KATO, R ;

KOBAYASHI, A ;

MORIYAMA, S ;

NISHIO, Y ;

KAJITA, K ;

SASAKI, W .

SYNTHETIC METALS, 1988, 27 (1-2) :A283-A288

[7] SYNTHESIS OF SYM-(E-Z)-DISELENADITHIAFULVALENE [J].

LAKSHMIKANTHAM, MV ;

CAVA, MP .

JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (13) :2632-2636

[8]

NIGREY PJ, 1988, SYNTHETIC MET, V27, pB365

[9] A NEW ONE-DIMENSIONAL METAL WITH CONDUCTION THROUGH BIS(DICYANOETHYLENEDITHIOLATO)PLATINUM ANIONS [J].

UNDERHILL, AE ;

AHMAD, MM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (03) :67-68

[10] FROM SEMICONDUCTOR SEMICONDUCTOR TRANSITION (42K) TO THE HIGHEST-12.5 K ORGANIC SUPERCONDUCTOR, KAPPA-(ET)2CU[N(CN)2]CL [J].

WILLIAMS, JM ;

KINI, AM ;

WANG, HH ;

CARLSON, KD ;

GEISER, U ;

MONTGOMERY, LK ;

PYRKA, GJ ;

WATKINS, DM ;

KOMMERS, JM ;

BORYSCHUK, SJ ;

CROUCH, AVS ;

KWOK, WK ;

SCHIRBER, JE ;

OVERMYER, DL ;

JUNG, D ;

WHANGBO, MH .

INORGANIC CHEMISTRY, 1990, 29 (18) :3272-3274