STUDIES OF THE GAUSSIAN MODEL .2. THE 2-COMPONENT SYSTEM

被引:9
作者
BARAM, A [1 ]
MADDOX, MW [1 ]
ROWLINSON, JS [1 ]
机构
[1] SOREQ NRC,DEPT ATMOSPHER OPT,IL-70600 YAVNE,ISRAEL
关键词
D O I
10.1080/00268979200101901
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A two-component version of the continuum Gaussian model shows a separation into two fluid phases at high densities. We analyse its behaviour by calculating the cluster integrals and virial coefficients up to 13th order for systems of dimensionality, d, from 2 to 10. We show that there is strong evidence that for d greater-than-or-equal-to 4 the system has a classical critical point but that its behaviour is quite different for d = 2 and 3. The best value of the critical exponent that governs the divergence of the susceptibility, gamma(rho), is 1.55 for d = 3, but a virial expansion to at least 20th order would be needed to give an accurate estimate and our result does not rule out the value of 1.39 that would be expected from a member of the Ising universality class.
引用
收藏
页码:1093 / 1101
页数:9
相关论文
共 9 条
[1]  
Austin T. L., 1960, CAN J MATH, V12, P535, DOI [10.4153/cjm-1960-047-1, DOI 10.4153/CJM-1960-047-1]
[2]   THE GAUSSIAN MODEL OF A FLUID IN DIMENSIONS D = 0, -2 - AN EXACT SOLUTION [J].
BARAM, A ;
LUBAN, M .
JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 1986, 19 (10) :L585-L588
[3]   STUDIES OF THE GAUSSIAN MODEL .1. THE ONE-COMPONENT SYSTEM [J].
BARAM, A ;
ROWLINSON, JS .
MOLECULAR PHYSICS, 1991, 74 (03) :707-713
[4]  
GUTTMAN AJ, 1989, PHASE TRANSITIONS CR, V13, pCH1
[5]   CRITICAL SOLUTION BEHAVIOR IN A BINARY MIXTURE OF GAUSSIAN MOLECULES .2. [J].
HELFAND, E ;
STILLINGER, FH .
JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (03) :1232-+
[6]  
Rowlinson J. S., 1980, ADV CHEM PHYS, V41, P1
[7]   CRITICAL SOLUTION BEHAVIOR IN BINARY MIXTURE OF GAUSSIAN MOLECULES [J].
STILLINGER, FH ;
HELFAND, E .
JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (08) :2495-&
[8]  
TEWARSON RP, 1971, SPARSE MATRICES, P91
[9]   PLAIT POINTS IN 2- AND 3-COMPONENT LIQUID MIXTURES [J].
WIDOM, B .
JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (09) :3324-&