RIETVELD ANALYSIS OF MECHANICALLY ACTIVATED POWDERED ZINC FERRITE

被引:32
作者
SEPELAK, V [1 ]
TKACOVA, K [1 ]
RYKOV, AI [1 ]
机构
[1] RUSSIAN ACAD SCI, INST SOLID STATE CHEM, NOVOSIBIRSK 630091, RUSSIA
关键词
D O I
10.1002/crat.2170280109
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The mechanically induced changes in structure and magnetic properties of zinc ferrite were investigated by using the Rietveld analysis and Mossbauer spectroscopy. The formation of the spin arrangement in mechanically activated zinc ferrite is connected with a redistribution of the cations in the close-packed anionic sublattice. On the basis of the Rietveld analysis the degree of mechanically induced inversion as well as the exact coordinates of atoms and lattice parameters in non-activated and mechanically activated ZnFe2O4 was determined.
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页码:53 / 56
页数:4
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