MOLAR AND PARTIAL MOLAR EXCESS VOLUMES OF DI-N-BUTYLAMINE WITH CHLOROALKANES AT 25-DEGREES-C

被引：19

作者：

ACEVEDO, IL ^{[1
]}

ARANCIBIA, EL ^{[1
]}

KATZ, M ^{[1
]}

机构：

[1] UNT,FAC CIENCIAS EXACTAS & TECNOL,INST INGN QUIM,CATEDRA FISICOQUIM,AVDA INDEPENDENCIA 1800,RA-4000 TUCUMAN,ARGENTINA

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1993年 / 22卷 / 02期

关键词：

DENSITIES; EXCESS MOLAR VOLUMES; PARTIAL EXCESS MOLAR VOLUMES; ERAS MODEL;

D O I：

10.1007/BF00650685

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molar excess volumes and partial molar excess volumes are reported for binary mixtures of dibutylamine + dichloromethane, trichloromethane and tetrachloromethane at 25-degrees-C, over the whole concentration range. A comparative study is made between the primary and secondary amines and their mixtures with chloroalkanes. The applicability of the so-called ERAS model for predicting thermodynamic excess properties is tested here for excess molar volumes; the calculated values agree quite well with experimental data.

引用

页码：191 / 200

页数：10

共 13 条

[1] MOLAR EXCESS VOLUMES AND PARTIAL MOLAR EXCESS VOLUMES OF NORMAL-BUTYLAMINE WITH CHLOROALKANES AT DIFFERENT TEMPERATURES [J].