COPPER(I) IODIDE COORDINATION POLYMER WITH TETRAKIS(ETHYLTHIO)TETRATHIAFULVALENE (TTC2-TTF) AND THE IODINE-DOPED COMPOUND

被引：34

作者：

GAN, XM ^{[1
]}

MUNAKATA, M ^{[1
]}

KURODASOWA, T ^{[1
]}

MAEKAWA, M ^{[1
]}

机构：

[1] KINKI UNIV, DEPT CHEM, OSAKA, OSAKA 577, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 11期

关键词：

D O I：

10.1246/bcsj.67.3009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex was synthesized by the reaction of copper(I) iodide and tetrakis(ethylthio)-tetrathiafulvalene (TTC2-TTF) in acetonitrile under argon atmosphere. The new compound, [(CuI)(2)TTC2-TTF], crystallizes in the monoclinic system, space group P2(1)/m with unit-cell dimensions a=9.843(2), b=12.946 (2), c=10.079(1) Angstrom, beta=99.91(1)degrees, V=1265.2(4) Angstrom(3), and Z=2. It is a neutral 2:1 (metal/ligand) complex in which each metal ion is tetrahedrally coordinated by two bridging iodide ions and two sulfur atoms from TTC2-TTF to form coordination polymeric chains. The average Cu-I and Cu-S bond lengths are 2.601 and 2.369 Angstrom, respectively. The complex was doped with iodine to afford [(CuI)(2)TTC2-TTF]I-1.5 which exhibits a conductivity of 2x10(-3) Scm(-1) at 25 degrees C for a compacted pellet.

引用

页码：3009 / 3011

页数：3

共 20 条

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