CHEMICAL-DEPOSITION OF ZINC HYDROXOSULFIDE THIN-FILMS FROM ZINC(II) - AMMONIA-THIOUREA SOLUTIONS

被引:21
作者
MOKILI, B
FROMENT, M
LINCOT, D
机构
[1] ECOLE NATL SUPER CHIM PARIS,ELECTROCHIM & CHIM ANALYT LAB,CNRS UNITE,F-75231 PARIS 05,FRANCE
[2] UNIV PARIS 06,CNRS,UPR PHYS SOLIDES LIQUIDES & ELECTROCHIM 15,F-75252 PARIS 05,FRANCE
来源
JOURNAL DE PHYSIQUE IV | 1995年 / 5卷 / C3期
关键词
D O I
10.1051/jp4:1995324
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The growth of ZnS films from ammonia solutions using thiourea as a sulfur precursor has been investigated, In situ growth kinetic studies have been performed by means of the quartz crystal microbalance (QCM) technique. The experiments have been carried out in pH buffered conditions (pH approximate to 11) and the effect of the addition of amines has been investigated. The film are characterized by various techniques (Optical, Rutherford Back Scattering, Transmission Electron Microscopy), The composition of zinc hydroxosulfide is ranging between almost pure ZnS to mainly Zn(OH)(2) depending on the deposition conditions.
引用
收藏
页码:261 / 266
页数:6
相关论文
共 17 条
[1]  
Borges R.O., 1992, 11 EC PHOT SOL EN C, P862
[2]  
BORGES RO, 1993, J ELECTROCHEM SOC, V140, P3464
[3]  
CHARLOT G, 1963, ANAL QUALITATIVE REA, P380
[4]  
Chopra K. L., 1982, PHYS THIN FILMS, V12, P167
[5]   PROCESS AND FILM CHARACTERIZATION OF CHEMICAL-BATH-DEPOSITED ZNS THIN-FILMS [J].
DONA, JM ;
HERRERO, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (01) :205-210
[6]   GROWTH-KINETICS AND POLYMORPHISM OF CHEMICALLY DEPOSITED CDS FILMS [J].
KAUR, I ;
PANDYA, DK ;
CHOPRA, KL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (04) :943-948
[7]  
KITAEV GA, 1971, RUSS J INORG CHEM, V16, P1683
[8]  
KITAEV GA, 1965, ZH FIZ KHIM+, V39, P1101
[9]  
KITEAV GA, 1975, RUSSIA J PHYS CHEM, V49, P275
[10]  
KLEIN DH, 1965, TALANTA, V12, P363